Novel Decavanadate Compounds for Lithium-Ion Batteries

En Route Towards a New Class of High-performance Energy Materials

Novel Decavanadate Compounds for Lithium-Ion Batteries

En Route Towards a New Class of High-performance Energy Materials

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Simon Greiner investigates the molecular-level stabilization of polyoxovanadate (POV) compounds by rational design for the application as active cathode material in lithium-ion batteries. Formation of a complex hydrogen-bonding network locks the POVs in place and prevents thermal decomposition during electrode fabrication. The molecular vanadium oxide clusters can be electrochemically analyzed and show promising results for storage of multiple electrons per cluster, making these materials highly attractive for energy storage applications. Analytical methods comprise ATR-FTIR, powder and single-crystal XRD, electron microscopy, EDX, electrochemical analysis and battery testing.

Polyoxometalates in General and Polyoxovanadates in Particular.- Lithium-Ion Batteries in General.- Stabilization of POMs by Crystal Engineering.- Electrochemical Characterization and Battery Testing of POM-based Electrodes.
ISBN 978-3-658-28984-3
Media type Book
Copyright year 2020
Publisher Springer, Berlin
Length XIX, 107 pages
Illustrations XIX, 107 p. 71 illus., 9 illus. in color.
Language English