Science of Synthesis: Houben-Weyl Methods of Molecular Transformations Vol. 47a
Alkenes
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1;Science of Synthesis - Volume 47a: Alkenes;11.1;Title page;31.2;Imprint;51.3;Preface;61.4;Volume Editor's Preface;81.5;Overview;101.6;Table of Contents;121.7;Introduction;221.8;47.1 Product Class 1: Alkenes;301.8.1;47.1.1 Synthesis by Alkenation Reactions;301.8.1.1;47.1.1.1 Wittig and Related Phosphorus-Based Alkenations;301.8.1.1.1;47.1.1.1.1 Monosubstituted Alkenes;311.8.1.1.1.1;47.1.1.1.1.1 Method 1: Synthesis from Aldehydes and Methylenetriphenylphosphorane;311.8.1.1.1.1.1;47.1.1.1.1.1.1 Variation 1: Wittig Alkenation with Methylenetriphenylphosphorane Generated In Situ;331.8.1.1.1.1.2;47.1.1.1.1.1.2 Variation 2: Wittig Alkenation with Methylenetriphenylphosphorane and Aldehyde Generated In Situ;361.8.1.1.1.1.3;47.1.1.1.1.1.3 Variation 3: Wittig Alkenation under Phase-Transfer Conditions;381.8.1.1.1.1.4;47.1.1.1.1.1.4 Variation 4: Synthesis of 13C- and 2H-Labeled Terminal Alkenes from Labeled Methyltriphenylphosphonium Halides;391.8.1.1.1.2;47.1.1.1.1.2 Method 2: Synthesis from Formaldehyde and Alkylidenetriphenylphosphoranes;411.8.1.1.2;47.1.1.1.2 1,1-Disubstituted Alkenes;431.8.1.1.2.1;47.1.1.1.2.1 Method 1: Synthesis from Ketones and Methylenetriphenylphosphorane;431.8.1.1.2.2;47.1.1.1.2.2 Method 2: Synthesis from Formaldehyde and Alkylidenetriphenylphosphoranes;471.8.1.1.2.2.1;47.1.1.1.2.2.1 Variation 1: Wittig Alkenation with Preformed Ylides and Formaldehyde in Aqueous Solution;471.8.1.1.2.2.2;47.1.1.1.2.2.2 Variation 2: Wittig Alkenation with Paraformaldehyde and Ylides Formed In Situ;481.8.1.1.3;47.1.1.1.3 Z-1,2-Disubstituted Alkenes;481.8.1.1.3.1;47.1.1.1.3.1 Method 1: Wittig Alkenation of Preformed Stable Aldehydes;491.8.1.1.3.1.1;47.1.1.1.3.1.1 Variation 1: Reaction under Homogeneous Conditions;491.8.1.1.3.1.2;47.1.1.1.3.1.2 Variation 2: Reaction with Immobilized Ylides;511.8.1.1.3.1.3;47.1.1.1.3.1.3 Variation 3: Reaction under Phase-Transfer Conditions;531.8.1.1.3.2;47.1.1.1.3.2 Method 2: Wittig Alkenation of Aldehydes Prepared In Situ;541.8.1.1.3.2.1;47.1.1.1.3.2.1 Variation 1: Alkenation of Aldehydes Prepared In Situ by Oxidation of Alcohols;541.8.1.1.3.2.2;47.1.1.1.3.2.2 Variation 2: Alkenation of Aldehydes Prepared In Situ by Reduction;581.8.1.1.3.2.3;47.1.1.1.3.2.3 Variation 3: Alkenation of Aldehydes Prepared by Oxidation of Ylides or Alkenes;611.8.1.1.3.2.4;47.1.1.1.3.2.4 Variation 4: Alkenation of Masked Aldehydes;621.8.1.1.3.3;47.1.1.1.3.3 Method 3: Alkenation with (Triphenylphosphoranylidene)alkanoates and -alkoxides;641.8.1.1.3.3.1;47.1.1.1.3.3.1 Variation 1: Ylide Generation with an Excess of Base;641.8.1.1.3.3.2;47.1.1.1.3.3.2 Variation 2: Alkenation with In Situ Silylated Alkoxide Ylides;661.8.1.1.3.4;47.1.1.1.3.4 Method 4: Z-Selective Wittig--Horner Alkenation;671.8.1.1.4;47.1.1.1.4 E-1,2-Disubstituted Alkenes;701.8.1.1.4.1;47.1.1.1.4.1 Method 1: The Schlosser Modification of the Wittig Alkenation;701.8.1.1.4.2;47.1.1.1.4.2 Method 2: E-Selective Wittig--Horner Alkenation;711.8.1.1.4.3;47.1.1.1.4.3 Method 3: E-Selective Alkenation with Ylides Bearing Substitutents Other Than Triphenylphosphine;731.8.1.1.5;47.1.1.1.5 Tri- and Tetrasubstituted Alkenes;751.8.1.1.5.1;47.1.1.1.5.1 Method 1: Non-Stereocontrolled Wittig Alkenations;751.8.1.1.5.1.1;47.1.1.1.5.1.1 Variation 1: Synthesis with Symmetrical Phosphoranes or Ketones;751.8.1.1.5.1.2;47.1.1.1.5.1.2 Variation 2: Synthesis with (Cycloalkylidene)triphenylphosphoranes;771.8.1.1.5.1.3;47.1.1.1.5.1.3 Variation 3: Synthesis with Unsymmetrical Phosphorus Ylides and Unsymmetrical Ketones;791.8.1.1.5.2;47.1.1.1.5.2 Method 2: Stereocontrolled Alkenations;821.8.1.1.5.2.1;47.1.1.1.5.2.1 Variation 1: The SCOOPY Procedure;821.8.1.1.5.2.2;47.1.1.1.5.2.2 Variation 2: With Phosphole-Derived Ylides;831.8.1.1.5.2.3;47.1.1.1.5.2.3 Variation 3: Horner--Emmons and Wittig--Horner Alkenations with Phosphonates and Phosphine Oxides;851.8.1.1.5.2.4;47.1.1.1.5.2.4 Variation 4: Indi
J. Ager, David
Meijere, Armin de
ISBN | 9783131784612 |
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Artikelnummer | 9783131784612 |
Medientyp | E-Book - ePUB |
Copyrightjahr | 2014 |
Verlag | Georg Thieme Verlag KG |
Umfang | 653 Seiten |
Sprache | Englisch |
Kopierschutz | Digitales Wasserzeichen |