Provides insights into the structure, mechanisms, and applications of metal nanocluster catalysis
 
Metal nanoclusters are rapidly emerging as a distinct class of catalysts with unique properties that bridge the gap between molecular and nanoparticle systems. Their ultra-small size, atomically precise structures, and diverse metal?metal and metal?ligand interactions give rise to catalytic behaviors that combine the best attributes of both homogeneous and heterogeneous catalysts. Nanoclusters demonstrate exceptional activity, selectivity, and recyclability, making them highly promising for applications across green chemistry and sustainable energy research.
 
Metal Nanocluster Catalysis: From Fundamentals to Applications provides a timely and thorough examination of this rapidly expanding field. Organized into twelve chapters, the book systematically introduces the three major classes of nanocluster catalysts?in-situ generated, supported, and ligand-protected systems?covering their formation, structural features, and mechanistic pathways. Beyond conventional catalytic transformations such as oxidation and borylation, the book highlights the growing role of nanoclusters in photo-, electro-, and enzyme-catalysis, where their exceptional energy and electron transfer capabilities open new avenues for organic transformations.
 
Integrating theoretical frameworks and emerging practical strategies in a single volume, Metal Nanocluster Catalysis:
 
* Explores applications in hydrogenation, oxidation, borylation, and cross-coupling reactions
* Discusses practical aspects of industrial catalysis, including recyclability and scale-up
* Provides insight into recyclability and large-scale applications in industrial catalysis
* Addresses the challenges and opportunities that define future research directions
* Includes commentary on current challenges and future research opportunities
 
Metal Nanocluster Catalysis: From Fundamentals to Applications is ideal for advanced undergraduates, graduate students, and researchers in catalysis, inorganic chemistry, chemical engineering, and materials science. It is well-suited for courses such as Advanced Catalysis, Nanomaterials in Chemistry, and Sustainable Energy Chemistry within degree programs in chemistry, chemical engineering, and materials science.

Preface
 
Chapter 1. Introduction to metal nanocluster catalysis
1.1 Catalysis and metal catalysts
1.2 Single metal atom, metal nanocluster and metal nanoparticle
1.3 Metal nanocluster catalysis: activity
1.4 Metal nanocluster catalysis: selectivity
1.5 Metal nanocluster catalysis: mechanism
 
Chapter 2. In-situ generated metal nanocluster catalysis
2.1 Catalytic hydrogenation
2.2 Catalytic oxidation
2.3 Catalytic borylation
2.4 Catalytic cross-coupling reactions
 
Chapter 3. Immobilized metal nanocluster catalysis
3.1 Carbon nanomaterial immobilized metal nanocluster
3.2 Metal or metallic oxide immobilized metal nanocluster
3.3 Polymer or supermolecule immobilized metal nanocluster
3.4 Dendrimer immobilized metal nanocluster
3.5 Biomolecule immobilized metal nanoclusters
3.6 New types of supports immobilized metal nanoclusters
 
Chapter 4. Organic ligand protected metal nanocluster catalysis
4.1 Synthesis, characterization and atomically precise structure
4.2 Thiolate-protected metal nanocluster for catalysis
4.3 Phosphine-protected metal nanocluster for catalysis
4.4 Alkyne-protected metal nanocluster for catalysis
4.5 Carbene-protected metal nanocluster for catalysis
4.6 Nitrogen-based ligand-protected metal nanocluster for catalysis
4.7 Isomeric metal nanocluster catalysis and nanocluster asymmetric catalysis
 
Chapter 5. Metal nanocluster photo-catalysis
5.1 Metal nanocluster photophysical property
5.2 Metal nanocluster photocatalytic property
5.3 Metal nanocluster energy transfer
5.4 Metal nanocluster electron transfer
 
Chapter 6. Metal nanocluster electro-catalysis
6.1 Metal nanocluster electrochemical property
6.2 Metal nanocluster heterogeneous electrode
6.3 Metal nanocluster homogeneous electrocatalyst
 
Chapter 7. Metal nanocluster enzyme-catalysis
7.1 Nano-enzyme and cluster-enzyme
7.2 Catalytic performance of metal nanocluster enzyme
 
Chapter 8. Metal nanocluster industrial catalysis
8.1 Metal nanocluster large-scale preparation
8.2 Metal nanocluster recyclability
8.3 Metal nanocluster catalysis in environmental and sustainable chemistry
 
Chapter 9. Conclusion and perspective
9.1 Metal nanocluster catalysis: opportunity
9.2 Metal nanocluster catalysis: challenge